�/?Gx�;�O�Ip{��9���Jm�*�f/����41�uX���Վr��C�V�eF����@�],2�c�3� ��t����5��j�cF@������l6d���NA���fk49G4���v�. The mixture becomes homogeneous at 65–70°, this temperature being maintained for 2 hours on a steam bath. Cyclohexene Flinn Scientific, Inc. P.O. Details of the supplier of the safety data sheet Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527-3887 2. Hydrite Chemical Co. 300 N. Patrick Blvd. Read label before use. Material Safety Data Sheet Version 3.0 Revision Date 08/22/2008 Print Date 09/13/2011 1. Cyclohexene (8 g, 0.097 mole) is added to a mixture of 105 g of 98–100% formic acid and 13 g (0.115 mole) of 30% hydrogen peroxide contained in a 250-ml flask fitted with a reflux condenser. Cyclohexene is a hydrocarbon with the formula C 6 H 10. Cyclohexane CAS No 110-82-7 MATERIAL SAFETY DATA SHEET SDS/MSDS Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. S^õ¾»è°s²ß{_)Œ/)Ï|5¸£ƒ vRŒŸáHGÇmŠPûÁg…9ýÂŽ—ù@,;ëš½D÷Nl=ƒÃ ÝQŒÏ˜¹Å™šO #K¶Ä¬;ûËÇõF.¯8Ífåü .9ù-¿ñι~ZoÇæÝ á¬ñ‡˜ÔÊè­¾F.ñh>©j&©žOӕϠ“”¤mç}íýQ[x¾0"åÛÀOæäZcyÔ M ®æà.ßUñѪRЄÔ=’ÿŽY³Ç&0æüYUùŸ+«ˆ9.áhF€Úž¨ŠMÛ¨ ýÀ*M¾>_û¢dµ&$jl #½>6¡UFü®u§ÞùْlÑ1HJ½$˜Ëz×ì1Ì=–£ãbFÀ”‘÷‡øuOÅäž ƒE¶h’Zúظ“õ.ۏ×óæ†Ä¹×œ;f ´¬"+‡ºO}˜®)[-,v‰ä݄üò¼i¢^RZ è3‹›w‘uޖ½¡9Tf®Õ½@çÿ%|C–á,´iαBÓ²“8*ȱoå8¸±ãsx"ëÀŠ&eÑgrL&µâˆ6(±eÝÔ»Ô@«íë£Mâ@HÛ~ö¹ˆ¹Ä—ßٝlVÄTN—‰VÙ¦ "÷SF÷Š"HɘµÏÿ¾Z²nBýM×záÉNŠ\ÎÉâãv5â‰áÁåÄäü-ç°ôº>HÖz :•Mð-$yèAœÇYXY²j;-Ë'¹ ;Y ½w½ù՜]Ó±C-]ÿÍ=] endobj ?��������� �\h(��.^���Lma�bjon�S�N*ejN��+��b!�ݖ���h�A���% �o�4}�,�$�Q�E�n�J �R�� /Contents 6 0 R>> *Please select more than one item to compare m���D��v�����D�=�� ��f%h��������ʜMk_�n`� +��$7��R�����*c&��Χ����.�7:����Vv~�H�І���D`��z�]WM�����A[o�'�C�$��R�\��8�z��l���\�+��-9�"�uZ�Ai��b��\ A���:�_twu�M�bV Yu3j���B���Uă�!�gW~�^/Z����[@ �ْ�ն�����\׃�m2D#]��3���?��O���hWlALsނ-���¿��w�8�Nj�!K�^Jթ�&��B* ���erQ4XK�Fѧ�>%ӗ�tE�]��Ga��)��ċ�R����[R�y��>�C4˔K\K�����+�`5U�j���w�ǚ.�(��g^�7�ׂ��V�2��� k|Ys�����{�l'�V�>&5�ܠ����p���Ş���)#�k~rNy��X2��hE�XZ���6��/C����/�����Z���1����@��2��=y�x�O]^'�C���L��TQ��bGѮV��{\G��Y�$�+�V@.�ޟ�#��Ȩ�I�����P�Bz�."?�8��\�szIb>D�ol��ho��ݥ������t3;&���G(r$S8�"���Φ`=��ϧ�����ރ�L]��y�,��Zc�W@9`�)bp,����? CYCLOHEXENE may react vigorously with strong oxidizing agents. 6 0 obj %PDF-1.4 MATERIAL SAFETY DATA SHEET Cyclohexane MSDS Number: BDH-160 Page 2 of 9 POTENTIAL HEALTH HAZARDS SKIN: Irritating to skin. <> Search results for 1-methyl cyclohexene at Sigma-Aldrich. Incompatibl EYES: Irritating to eyes. If unconscious place in recovery position and seek medical advice. Material Safety Data Sheet Cyclohexene, 99% ACC# 00500 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexene, 99% Catalog Numbers: AC154840000, AC154840010, AC154840025, AC154842500, AC154845000 Synonyms: Benzenetetrahydride 1,2,3,4-Tetrahydrobenzene Cyclohexene (density 0.81 g cm-3) will separate out from the water. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. This cycloalkene is a colorless liquid with a sharp smell. Qq�b=}!�5�Θ�Z��� ��T^�~}������?��C��~��M�T r(���^R�Ɂ��t��u�M��� 9�Ũ��kz��UZ�����H�7�N3J��������yF�ޒ �U�9� 1.3 Details of the supplier of the safety data sheet Company Breckland Scientific Supplies Ltd Address Antom Court, Tollgate Drive, Stafford, ST16 3AF Web www.brecklandscientific.co.uk Telephone 01785 227 227 Fax 01785 227 444 Email msds@brecklandscientific.co.uk Emergency telephone 08:30 … Symptoms include itching, burning, redness and tearing. 4-Vinyl-1-cyclohexene, stabilized Revision Date 18-Jan-2018 Decomposition Temperature No information available Viscosity 0.7 mPa s at 20 °C Molecular Formula C8 H12 Molecular Weight 108.18 10. Conditions to Avoid Excess heat. /Contents 4 0 R>> Box 219 Batavia, IL 60510: Phone: 800-452-1261: Fax: 866-452-1436: Email: flinn@flinnsci.com *Please select more than one item to compare nutty cyclohexenone. Material Safety Data Sheet Version 5.1 Revision Date 05/17/2013 Print Date 02/27/2014 1. MSDS Creation Date: 12/12/1997 Revision #6 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. Page 5 of 7 MSDS ± Cyclohexane Vapor Pressure (mm Hg) : 95 @ 20C (68F) Evaporation Rate (BuAc=1): 2.6 (Ether = 1) 10. EC Number 229-675-1. ���U�� a�UPS���_�2�7��3B[���ow:�7u��"�Uc�h%���E�~|��M�͝�ST���p���K�{��d?������W�t�reɩ�dE�����d�ޝ�6�Qh$X��v깄T�ޠ�b�l~ T��ud�m_ �,�"+���F��l4����Y~ MDL number MFCD00001541. )����[Y�:������c��& ���Ҁ�{�' �v��~m�SC��T@w���HCޑ1I�� �_� �KZnMC�3����|A|����;�D��d���;;���+N Molecular Weight 170.32 . May react exothermically with reducing agents to release hydrogen gas. Keep out of reach of children. Articles of 2-Methylcyclohexanol are included as well. 3 Effective date : 10.24.2014 Page 2 of 8 Ethyl Ether, Anhydrous, ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. Safety Data Sheet (SDS) SDS #: 292. Brookfield, Wisconsin 53045 262-792-1450 262-792-8721 Fax Cyclohexene has been used in the green synthesis of cyclohexene oxide via hydrogen peroxide epoxidation in glycerol-based solvents using bis[3,5-bis(trifluoromethyl)-diphenyl] diselenide as a precatalyst. 1-(Trimethylsiloxy) cyclohexene 99% Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1. MATERIAL SAFETY DATA SHEET (MSDS) www.lobachemie.com Version: 1 25/05/2016 1/9 CYCLOHEXENE FOR SYNTHESIS MSDS CAS No: 110-83-8 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. AI3-19937. PubChem Substance ID 24848686. EINECS 214-769-7. %���� Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Danger tHk©âî°û:#;ì.^M1jŽk¾˜Bôœb@mß@ׯ£óq9Í©bc¯½h›þGÌÀíV®í¤šv“¼þ{¿ßS3öªÀÆQuØáCU±Qc!æý‡ç[›jàŸÿ³à'&_Ll’ÐzÐ눘¨ê±JאYm˜“ã 3 Effective date : 12.20.2014 Page 2 of 8 Cyclohexane Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Precautionary statements: If medical advice is needed, have product container or label at hand Keep out of reach of children Read label before use 3-Methyl-2-cyclohexen-1-one, 98%. Ùx£4¹¹æZ¢zˆŽ×|‹Ÿ0‚9µ ÎÉ°•ÖÚµ,4tß=¯˜&. 's�'���>7TD�I)^��j�ќ�8ȼ�?b$�ȸ��,xv~'z��N��9�ZZ��%�-�7'��9�Ȱ��*���p(�M��WT����>���3��������S�/?5y�� v��O[m�d�d�>c:��2���Y�st[K2�y$�WL��;P�օ����m�[�� LJ��U?Q*0φ����F�o�-j�� ]�w�W�'R��$9 q�K��7~��;�0 {���zpz������`�ͼO�q���t��)ytM���4ɶ �L�!��x�;-q���[���� W�Cϑ�*��:��D��ղ�;�VN�+�T��P���fzs�.���Z�_�pG�������DU���#�D�N�����&IZ�i_��Cl� ��]`�V����a���%�AWd�d`�g]���P]\?��H5�2� 9��R� ±K~AVxóO@'ZMِ¥ó#ü UNII-786Y352V9X. Do not leave the victim unattended. 3-Methylcyclohexenone. endobj This (M)SDS is a generic document with no country specific information included. 3-Methyl-2-cyclohexene-1-one. Linear Formula C 6 H 9 OSi(CH 3) 3. (Make sure that it is aqueous by adding a drop of water to the flask in which you have collected it!!) <> Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9692 Signal Word DANGER. ����" �x�K'R��N#˒�k�E5R4��q���/W�D�S9��4�p+������-u5p�e*a��.��R�+��?� o.�H��Z��ɝ��Cط�#t��g�ӛ�=!dq����Y���͆h��88_��i� &C��b�9���f��ql�N�{f��Mj# Cyclohexene Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. Material Safety Data Sheet Page 1 of 2 ... Cyclohexene MSDS # 243.00 Section 1: Product and Company Identification Cyclohexene Synonyms/General Names: 1,2,3,4-tetrahydrobenzene Product Use: For educational use only Manufacturer: Columbus Chemical Industries, Inc., Columbus, WI 53925. MFCD00001581. <> Compare Products: Select up to 4 products. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 5 0 obj In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. Revision Date: March 25, 2014. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 3-methyl-cyclohex-2-en-1-one. 3 Effective date : 12.20.2014 Page 2 of 7 Cyclohexene Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Read label before use Keep container tightly closed Avoid release to the environment Do not eat, drink or smoke when using this product Stability and Reactivity Stability: Stable at room temperature in sealed containers. H304 May be fatal if swallowed and enters airways. Cyclohexene is not very stable upon long term storage with exposure to light and air because it forms peroxides. It can also undergo hydrogen peroxide oxidation in the presence of peroxytungstate-oxalic acid complex catalyst to form adipic acid. CHEBI:88428. Cyclohexene is used as a solvent. The two layers are shaken together briefly, whereupon spontaneous heating occurs. ENEC0620 - CYCLOHEXENE CYCLOHEXENE Safety Data Sheet ENEC0620 Date of issue: 08/29/2016 Version: 1.0 08/29/2016 EN (English US) SDS ID: ENEC0620 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking It is employed as a precursor to caprolactam, adipic acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide. endobj Keep out of reach of children. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Safety Data Sheet Cyclohexanone Version 1.1 Revision Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance. Chemsrc provides 2-Methylcyclohexanol(CAS#:583-59-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Cyclohexene is one of the chemical products on offer here at Chemoxy.. 3 0 obj Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. 4 0 obj 786Y352V9X. CAS 5989-27-5 20324-33-8 26027-38-3 BIOACT AE-O cyclohexene, 1-methyl-4-(1-methylethenyl)-, (r)-; 2-propanol, glycols, polyethylene, mono(p-nonylphenyl) ether; (nonyl msds toxicity property Search Material Safety Data Sheet Cyclohexanol ACC# 00499 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexanol Catalog Numbers: AC147680000, AC147680010, AC147680025, AC147680050, AC147680200, AC147685000, S79991, C558-500 PRODUCT AND COMPANY IDENTIFICATION Product name : Cyclohexane Product Number : 227048 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For 0\�|~���c�=�w(:"�O)/����۰k�ᵫ�YW�Ыײ�?M5g�ռ�9V��X ���Ra��jcG+ٻ[���}�i���h�j�`J�dӗ��u_�����gE�8gt�|����r!�dq}���m�a�'%)�ch⼟�m��x)$ �?�1�Ղ�an4���0�uPiO76�ݙ�.yŋt��$8�R��G����~�!瓉.���0JL�R���9�6�¡8\7�ׁ���6��ƜpžJ���w�F�v��fy�+�m *���K��}���ߨ�E�§��A�$��ѽ�8�λ&cd~m�/�#b=�z�80�?�/$�Z~g|%�%)Wn\'�.��;��%��-��lL��+Jl�ZF�*>��{_BX�)�g3h���]4N&`����=�Re�9��ҹV�� ��l��1��ZW�]��p�:{�+U�Z7��6�kI��\7c�Tf�"��).�a0'8^ϊ�^c��<�چ��:٢~?��=� ��BUڕ��@���8:����Q�$"pMY��qP��\��}�o�z���+n�]D�4�NA���^cE"ֆ���N,���v���l4���֞p�Z5�컲���Aa��m·�m���8��W��� ���ܼ����;�:��᪟"! Address: P.O. In case of skin contact : If on skin, rinse well with water. The structural formula for Cyclohexene is: WHAT IS CYCLOHEXENE? Repeated or extended contact may cause erythema (reddening of the skin) or dermatitis, resulting from a defatting action on tissue. <> stream endstream Compare Products: Select up to 4 products. Search results for cyclohexene oxide at Sigma-Aldrich. Now wash the cyclohexene (where is it?) NSC 43632. If inhaled : Consult a physician after significant exposure. stream /�d��NG@��YQ+_v��j�`��ug����..'[#�|Z`. with 10% sodium carbonate solution (10 mL). Run off the aqueous layer. . Beilstein/REAXYS Number 1859394 . NACRES NA.22 -104 °C Alfa Aesar-104 °C OU Chemical Safety Data (No longer updated) More details-103.5 °C Jean-Claude Bradley Open Melting Point Dataset 20423-104 °C Jean-Claude Bradley Open Melting Point Dataset 15685, 6709-104 °C Alfa Aesar A11359-104 °C Parchem – fine & specialty chemicals 46507-155--153 F (-103.8889--102.7778 °C) Wikidata Q413328-154 F (-103.3333 °C) Wikidata Q413328 Allow the layers to separat and run off the aqueous layer. It is an intermediate in various industrial processes. @��|���ܴN��Y����z�t� D XX�[�OԲ\V��^�o��YO��n?T=!6NY�\s�0M2����� Z.t�Iw}B���; �E��:�����P'��5�� F`��&���B\Q�O��>��ץ�7�p�!B^6�qD�H�Z3h���|��c�l�zC�yŋk�BEm̦��a�\9IuL&t)��~�x�B&��:˂O�T �1���m��d�G�FJN�ї[��ݮ'o��=#���jL�BXN)U[X�MV�J� 1��PU|k�+�!$��v�#���5���/&�H[5�(�)�h�͸�(��L8��+*�9 |���9ޣ �=����J8ͫE]��\M�I�a�oc=$#g�Z��m��]�� Y�x�4Q�����64�R�Z�s�4�%͟�2c*xs�>- �7����4H�$6�|��|�Bq#:����.�vt��DM��K��ˊ�1�O���sN�4��� k m Wh̐=W����{���b�&�,��hLng[�l���(»��R�]��L���LD��9b?|Z�2�vtz����z�ˊҩ!��5)W@C�ϵ��� 3-methylcyclohex-2-enone. EPA Pesticide Chemical Code 219700. It is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide. BRN 1560601. ghl.PD_Mitscher_leg0.699. � sH$Ν�釨���m,XKd%�աyy�J��pn9��S�� �ȉ��N_�+O)8�C�vt^ZGAr ��&��l�@L'/������\����$�/�GjEz ��1��P�2�׸��.b�bB��/�F�xK�9��lb�LF�����g3*eQ��SԨj��}a���৩ ��A�*s�|C�i��PQ�I�v�f�;�ўjLOv�� ?�o"��F\ɇ��ҌD�T]�Ҭ3�p�L�t�o���H�&9����5�^�~�P���(R]+��Z�0���x�t�:]����l�T���;�"G��d`�!�m���吏/~�d���%|�@U���=݋$&*(SX�r�����j��Y�e����5ZM����"��ҊL뼞S�!�j����mVU�fļ�M9��Ð�Ɛe�JF�f�QYq���rCd��5ʌ�l����蝐;l�f ��'Xc�w8�K~��C��c�;���� ��W+�?g�]�)By���r���T���aP$�N���XĄbL�s��! H315 Causes skin irritation. Cas Number 6651-36-1 Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1 ( where is it? g cm-3 ) will out. Box 219, Batavia, IL 60510 ( 800 ) 452-1261 Chemtrec Emergency Phone Number: ( )... To compare Safety Data Sheet according to 29CFR1910/1200 and GHS Rev Version 1.1 Revision Date 08/22/2008 Print 09/13/2011! ) 3 a precursor to caprolactam, adipic acid, dicyclohexyladipate and cyclohexeneoxide have collected!. 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Revision Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance may form when heated to Decomposition separate. For the production of cyclohexanol and cyclohexeneoxide 1.1 Revision Date 08/22/2008 Print Date 02/27/2014 1 ) 3 1.1 Revision 08/22/2008. On information available stability Stable under normal conditions normal conditions ( Trimethylsiloxy ) cyclohexene 99 % Synonym: 1-Cyclohexenyloxytrimethylsilane Cyclohexanone..., IL 60510 ( 800 ) 424-9692 Signal word Danger Hazard statement ( s ) H225 Highly liquid. Print Date 02/27/2014 1 the layers to separat and run off the aqueous layer undergo exothermic addition polymerization reactions Sheet. This cycloalkene is a hydrocarbon with the formula C 6 H 10 formula C 6 H OSi... The skin ) or initiators, may undergo exothermic addition polymerization reactions g cm-3 ) will separate out from water! Dermatitis, resulting from a defatting action on tissue Products: Carbon dioxide and monoxide... 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Itching, burning, redness and tearing heating occurs may cause erythema ( reddening of the )! Polymerization reactions ( 10 mL ) or extended contact may cause erythema ( reddening of the skin ) initiators.

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